Abstract
Coordinated 1-phenyl-3,4-dimethylphosphole in the chiral complex chloro{( S)-1-[1-(dimethylamino)ethyl]naphthyl- C 2,N }[1-phenyl-3,4-dimethylphosphole- P]palladium behaves as an activated cyclic diene in the inter-molecular Diels–Alder reaction with 1-methyl-2-vinylpyrrole to give a pair of diastereomeric P-chiral endo-cycloadducts. The diastereomeric palladium complexes could be separated by fractional crystallization and the enantiomerically pure phosphanorbornene ligands could be liberated individually from the complexes by treatment with potassium cyanide. In contrast, the [4+2] cycloaddition reaction did not occurred under similar conditions when the chloro ligand in the phosphole complex was replaced with a perchlorato ligand.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
