Abstract

The asymmetric unit of the title compound, C10H17N3S, consists of three symmetry-independent mol­ecules with distinctly different conformations, as indicated for example by the C—N—C—C torsion angles of −155.9 (3), 89.9 (3) and 81.1 (4)° along the bond between thio­urea and allyl units. In the crystal, mol­ecules are connected via N—H⋯N and N—H⋯S hydrogen bonds into chains extending along [110] that are further associated through C—H⋯N inter­actions into layers parallel to (001). The allyl group in one of the independent mol­ecules is disordered over two sets of sites with an occupancy ratio of 0.853 (6):0.147 (6).

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