Abstract

In the molecules of the title compound, C14H11N3O3S, there is an intramolecular N—H⋯O hydrogen bond [2.635 (3) Å] between the amide N and benzoyl O atoms which completes a nearly planar six-membered ring in the central part of the molecule. The benzene rings of the benzoyl and nitrophenyl moieties form angles of 30.5 (4) and 35.7 (4)° with the plane of this hydrogen-bonded ring. In the crystal, molecules are connected into infinite zigzag chains by N—H⋯O bonds and these chains are linked across centres of symmetry by weak N—H⋯S interactions, thus forming a two-dimensional network. Van der Waals interactions between layers lead to a crystal structure with one very short axis (4 Å).

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