Abstract
Zn(dabcoH)Cl3 (dabco is 1,4-bicyclo[2.2.2]octane), [ZnCl3(C6H13N2)], crystallizes as a neutral monomeric species with approximate C3 symmetry. The tetrahedrally coordinated ZnII ion has Zn—Cl distances ranging from 2.239 (2) to 2.250 (2) Å and a Zn—N distance of 2.094 (4) Å. The Cl—Zn—Cl angles are slightly larger than tetrahedral [112.44 (6)–114.38 (6)°]. The protonated aza group forms a weak interaction with a Cl atom of an adjacent molecule.
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