Abstract
Considered as an essential intermediary at the biogenesis crossroads of most of the Erica cinerea 1,9-diarylnonanoids, the highly anticipated and sought β-ericadione is finally isolated as a glycoside. Accompanied by the newly reported ericanone 3-O-galactoside as well as mixed s-trans and s-cis conformers of α-ericadione 3-O-galactoside, it stands itself currently only as 3-O-galactoside split into the major 5-keto-enol tautomer. Unlike all other E. cinerea 1,9-diarylnonanoid glucosides, it does not seem currently having a glucoside correspondent within this species.
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