Abstract
AbstractThe etherification and amination of difluoroenol silyl ethers with benzoquinones and quinonediimines were achieved by using hexafluoroisopropanol (HFIP) as the solvent. This 1,6‐addition reaction could construct difluorooxymethyl and difluoroaminomethyl compounds under metal‐free conditions. It is preliminarily speculated that the reaction took place through a single electron transfer (SET) process.
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