Abstract
The title compound, C6H14N2 2+·2C7H4ClO2 −, contains trimeric units linked by N—H⋯O hydrogen bonds. The carboxylate groups of the 2-chlorobenzoate anions form dihedral angles of 66.1 (1) and 76.1 (1)° with the respective chlorobenzene rings to which they are bound. The hydrogen-bonded trimers are arranged in layers in the (200) planes and the chlorobenzoate anions form edge-to-face interactions between layers, with dihedral angles of 61.9 (1) and 49.8 (1)° and centroid–centroid distances of 4.85 (1) and 4.65 (1) Å, respectively, for two crystallographically distinct interactions.
Highlights
The title compound, C6H14N22+Á2C7H4ClO2À, contains trimeric units linked by N—HÁ Á ÁO hydrogen bonds
The hydrogenbonded trimers are arranged in layers in the (200) planes and the chlorobenzoate anions form edge-to-face interactions between layers, with dihedral angles of 61.9 (1) and 49.8 (1) and centroid–centroid distances of 4.85 (1) and 4.65 (1) A, respectively, for two crystallographically distinct interactions
R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger
Summary
The carboxylate groups of the 2-chlorobenzoate anions form dihedral angles of 66.1 (1) and 76.1 (1) with the respective chlorobenzene rings to which they are bound. The hydrogenbonded trimers are arranged in layers in the (200) planes and the chlorobenzoate anions form edge-to-face interactions between layers, with dihedral angles of 61.9 (1) and 49.8 (1) and centroid–centroid distances of 4.85 (1) and 4.65 (1) A , respectively, for two crystallographically distinct interactions. Related literature For other co-crystals of 1,4-diazoniabicyclo[2.2.2]octane and carboxylic acids, see: Meehan et al (1997); Burchell et al (2000); Burchell, Glidewell et al (2001); Burchell, Ferguson et al (2001). For the crystal structure of 2-chlorobenzoic acid, see: Ferguson & Sim (1961).
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
More From: Acta Crystallographica Section E Structure Reports Online
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.