Abstract
Abstract1,3‐Dipolar cycloaddition to C70 of an azomethine ylide, which was generated in situ from refluxing a mixture of cyclohexanone and DL‐valine in chlorobenzene under N2, afforded a monoadduct and a bisadduct. Even for longer reaction time, however, only monoadduct waa obtained from the reaction of C70 with an azomethine ylide generated from refluxing a mixture of 2‐undecanone and 2‐aminoisobutyric acid in chlorobenzene under N2. The electrochemical properties of all the products were studied by cyclic voltammetry.
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