Abstract
In the paper by Buchmeiser et al. published in 1, the structural assignment of compound 15 is incorrect. The correct structural assignment for this compound is [Ag(1,3-dimesityl-3,4,5,6-tetrahydropyrimidin-2-ylidene)2][Pd2Br2Cl4]1/2. Consequently, the X-ray structural assignment reported needs to be replaced. The correct structure has been deposited using the identical CCDC-No. 222718 with the Cambridge Crystallographic Data Center. The correct analysis for 15 is as follows: [Ag(1,3-dimesityl-3,4,5,6-tetrahydropyrimidin-2-ylidene)2][Pd2Br2Cl4]1/2 (15): 13C NMR (CD2Cl2): δ = 207.3 (CAg, 1J (107Ag,13C) = 174 Hz, 1J (109Ag,13C) = 202 Hz), 144.3, 139.9, 136.7, 131.4 (aromatic C), 45.54, 45.47 (NCH2), 22.7, 22.4, 19.4 ppm (CH3 of Mes + CH2); FABMS: m/z (%): calcd for C44H56N4Ag: 749.35 [M+]; found: mz: 749.35 (98.5). Other analytical data reported are correct. The authors sincerely apologize for this error.
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