Abstract
The title compounds, [N,N'-bis (2-pyridylcarbonyl)-propane-1,3-diaminato-κ 4 N]paliadium(II) monohydrate, [Pd(C 15 H 14 N 4 O 2 )].H 2 O, and [N,N'-bis(2-pyridylcarbonyl)propane-1,3-diaminato-κ 4 N]nickel(II) monohydrate. [Ni(C 15 H 14 N 4 O 2 )].H 2 O, were investigated by means of X-ray diffraction and high-resolution NMR. The Pd II and Ni II ions have regular and distorted square-planar coordination geometries, respectively. Libration of the propanediyl chains in these complexes was observed in both the crystalline and solution states.
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More From: Acta Crystallographica Section C Crystal Structure Communications
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