Abstract

General protocols for the construction of various ring systems employing cation olefin cyclizations initiated by the readily accessible 1,3-benzodithiolium ion are described. Several substituted tetralones and tetralins can be rapidly assembled by this methodology as can a variety of substituted bicyclo[3.2.1]octane and tricyclic ring systems. The products of these transformations are amenable to interconversion into a range of functionalized species

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