Abstract
The title molecule, C34H28I4·4C6H6, has crystallographic symmetry and crystallizes with four symmetry-related benzene solvent molecules. The phenyl group is eclipsed with one of the adamantane C—C bonds. The tetraphenyladamantane units and the benzene solvent molecules are connected by weak intermolecular phenyl–benzene C—H⋯π and benzene–benzene C—H⋯π interactions. In the crystal, molecules are linked along the c-axis direction via the iodophenyl groups by a combination of weak intermolecular I⋯I [3.944 (1) Å] and I⋯π(phenyl) [3.608 (6) and 3.692 (5) Å] interactions.
Highlights
The title molecule, C34H28I44C6H6, has crystallographic 4 symmetry and crystallizes with four symmetry-related benzene solvent molecules
The tetraphenyladamantane units and the benzene solvent molecules are connected by weak intermolecular phenyl–benzene C—H
Molecules are linked along the c-axis direction via the iodophenyl groups by a combination of weak intermolecular
Summary
Prisnerb a Institut für Organische Chemie, Universität Frankfurt, Max-von-Laue-Strasse 7, D-60438 Frankfurt am Main, Germany, and bInstitut für Physikalische und Theoretische Chemie, Universität Frankfurt, Max-von-Laue-Strasse 7, D-60438. R factor = 0.040; wR factor = 0.105; data-to-parameter ratio = 20.9. The title molecule, C34H28I44C6H6, has crystallographic 4 symmetry and crystallizes with four symmetry-related benzene solvent molecules. The phenyl group is eclipsed with one of the adamantane C—C bonds. The tetraphenyladamantane units and the benzene solvent molecules are connected by weak intermolecular phenyl–benzene C—H and benzene–benzene C—H interactions. Molecules are linked along the c-axis direction via the iodophenyl groups by a combination of weak intermolecular
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