Abstract
AbstractThe first example of the anionic [1,2]‐shift taking place in the metal coordination environment is described. The α‐thiobenzylated glycine in the form of the Ni(II) Schiff‐base complex is converted into the corresponding cysteine derivative with ca 70 % yield. The reaction disclosed emphasizes how the reactivity of a substrate can be influenced by noncovalent interactions in the metal coordination environment.
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