Abstract

In the title compound, C24H21ClN4O2S, the two adjacent spiro junctions link an almost planar (r.m.s. deviation = 0.017 Å) 2-oxindole ring, a hexa­hydro-1H-pyrrolizine ring and a tetra­hydro­imidazo[2,1-b]thia­zole ring. In the crystal, inversion dimers linked by pairs of N—H⋯N hydrogen bonds occur, generating an R 2 2(16) loop.

Highlights

  • Crystal data10 -(2-Chlorophenyl)-5,6,50 ,60 ,70 ,7a0 -hexahydro-10 H,10 0 H-dispiro[imidazo[2,1-b][1,3]thiazole-2,20 -pyrrolizine-30 (20 H), 0 indole]-20 0 ,3(2H,30 0 H)-dione

  • Inversion dimers linked by pairs of N—H N hydrogen bonds occur, generating an R22(16) loop

  • H atoms treated by a mixture of independent and constrained refinement max = 0.41 e Å3

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Summary

Crystal data

10 -(2-Chlorophenyl)-5,6,50 ,60 ,70 ,7a0 -hexahydro-10 H,10 0 H-dispiro[imidazo[2,1-b][1,3]thiazole-2,20 -pyrrolizine-30 (20 H), 0 indole]-20 0 ,3(2H,30 0 H)-dione. R factor = 0.043; wR factor = 0.113; data-to-parameter ratio = 13.6. C24H21ClN4O2S, the two adjacent spiro junctions link an almost planar (r.m.s. deviation = 0.017 Å) 2oxindole ring, a hexahydro-1H-pyrrolizine ring and a tetrahydroimidazo[2,1-b]thiazole ring. Inversion dimers linked by pairs of N—H N hydrogen bonds occur, generating an R22(16) loop

Related literature
Data collection
Multilayer monochromator
Special details
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