Abstract
AbstractThe 1,2‐metallate rearrangement occurring with boronate complexes is a strategy of choice for the synthesis of organoboron compounds, giving a direct access to highly functionalized molecules. Lately, significant progress has been made in the use of this reaction for the opening, the functionalization, and the formation of strained cycles. In this review, we will highlight these recent advances, focusing on cycloalkanes and oxygen‐ or nitrogen‐containing strained cycles.
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