Abstract
Pi in the sky: 1,2-bis(ferrocenyl)distibene and 1,2-bis(ferrocenyl)dibismuthene derivatives, where two bulky ferrocenyl units are bridged by a SbSb and BiBi π spacer, have been synthesized as a new family of novel d–π conjugated systems. Their molecular structures, spectroscopic behavior, and electrochemical properties reveal the SbSb and BiBi units to be effective π-electron spacers.
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