1,2-Bis(5-(trinitromethyl)-1,2,4-oxadiazol-3-yl)diazene: a water stable, high-performing green oxidizer.

Abstract

Trinitromethane moieties are very important for the design and development of high performing dense green oxidizers. The novel oxidizer 1,2-bis(5-(trinitromethyl)-1,2,4-oxadiazol-3-yl)diazene, 14 is stable in water in contrast to 1,2,4-oxadiazoles with other electron withdrawing substituents at the C5-position. Compound 14 is a CNO-based oxidizer with positive oxygen balance (+6.9%), moderate thermostability, and mechanical insensitivity that may find useful applications in the field of green rocket propallant.