Abstract
The title compound, C11H16O7, was obtained from the breakage reaction of the glycosidic bond of 5′-deoxy-2′,3′-diacetylinosine. The ribofuranose ring has a C2-exo, C3-endo twist configuration. No alteration of the relative configuration compared with d-(−)-ribose is observed.
Highlights
The title compound, C11H16O7, was obtained from the breakage reaction of the glycosidic bond of 50 -deoxy-20,30 diacetylinosine
The title compound was prepared from the reaction of the breakage of the glycosidic bond of 5′-Deoxy-2′,3′-diacetylinosine, which was gained from inosine by halogenation, hydrogenization and acetylation in turn. 5′-Deoxy-2′,3′-diacetylinosine (6.72 g, 20 mmol) and cation-exchange resin (6 g) were added to a solution of acetic anhydride/acetic acid (60 ml, 9: 1), was heated to 358 K and reacted under stirring for 8 h
The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry
Summary
R factor = 0.041; wR factor = 0.133; data-to-parameter ratio = 8.1. The title compound, C11H16O7, was obtained from the breakage reaction of the glycosidic bond of 50 -deoxy-20 ,30 diacetylinosine. The ribofuranose ring has a C2-exo, C3-endo twist configuration. No alteration of the relative configuration compared with d-()-ribose is observed
Sign-in/Register to view highlights & summary Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Acta Crystallographica Section E Structure Reports Online
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
