Abstract
In the title complex, [Mn(C6H2N3O7)2(C30H26N4O)], the MnII atom is coordinated by the tridentate bis-benzimidazole ligand and two atoms of the picrate anions, in a distorted square-pyramidal geometry (τ = 0.038). One nitro O atom of one picrate ion is disordered over two sites with occupancies of 0.54 (5) and 0.46 (5).
Highlights
In the title complex, [Mn(C6H2N3O7)2(C30H26N4O)], the MnII atom is coordinated by the tridentate bis-benzimidazole ligand and two atoms of the picrate anions, in a distorted squarepyramidal geometry ( = 0.038)
One nitro O atom of one picrate ion is disordered over two sites with occupancies of 0.54 (5) and 0.46 (5)
For the computation of the parameter describing the distortion of a square-pyramidal geometry, see: Addison et al (1984)
Summary
In the title complex, [Mn(C6H2N3O7)2(C30H26N4O)], the MnII atom is coordinated by the tridentate bis-benzimidazole ligand and two atoms of the picrate anions, in a distorted squarepyramidal geometry ( = 0.038). One nitro O atom of one picrate ion is disordered over two sites with occupancies of 0.54 (5) and 0.46 (5).
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