Abstract

A preparative method for the synthesis of 1,1-bis(diphenylphosphinoyl)ethanol (1) has been elaborated. In CHCl3 and MeCN solutions compound1 is associated into H-bonded dimers (-ΔH ≈ 12 kcal mol−1). Complexes of compound1 with NdIII, CuII, and CuI nitrates have been studed. The H-bonded dimers are retained upon complexing.

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