Abstract

AbstractSome enamines derived from α‐diketones have been reacted with tosylazide yielding unstable 5‐amino‐υ‐triazolines, which were found to undergo cyeloreversion to diazo compounds and arnidines. In the case of the enamines derived from 4‐aryl‐2,3‐butanediones, a competitive rearrangement to (Z)‐4‐aryl‐4‐arnino‐3‐tosylamino‐3‐butene‐2‐ones was observed.

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