Abstract
The dinuclear title compound, [Zn2(C7H14NS2)4(C12H10N2)], is centrosymmetric about the central C=C bond. The five-coordinate Zn atom is bonded to two asymmetrically chelating dithiocarbamate ligands and a pyridine N atom to define an NS4 coordination geometry tending towards a square pyramid, with the N atom in the apical site. In the crystal structure, C—H⋯S contacts lead to supramolecular chains.
Highlights
Data collectionT. River Rd, Columbus, Ohio 43202, USA, and cDepartment of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia
The cell s.u.'s are taken into account individually in the estimation of s.u.'s in distances, angles and torsion angles; correlations between s.u.'s in cell parameters are only used when they are defined by crystal symmetry
The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2
Summary
T. River Rd, Columbus, Ohio 43202, USA, and cDepartment of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia. Key indicators: single-crystal X-ray study; T = 98 K; mean (C–C) = 0.004 Å; R factor =. 0.038; wR factor = 0.103; data-to-parameter ratio = 21.5. The dinuclear title compound, [Zn2(C7H14NS2)4(C12H10N2)], is centrosymmetric about the central C C bond. The fivecoordinate Zn atom is bonded to two asymmetrically chelating dithiocarbamate ligands and a pyridine N atom to define an NS4 coordination geometry tending towards a square pyramid, with the N atom in the apical site. H S contacts lead to supramolecular chains
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