Abstract
The influence of the second coordination sphere of titanium complexes on the charge transfer kinetics of the Ti (IV)/Ti (III) redox couple in melts of alkali metal halides was studied by cyclic voltammetry method. Diffusion coefficients in the CsC-CsF (10 wt. %) melt were calculated. The standard rate constants of charge transfer have been determined by the Nicholson method. The activation energies of the charge transfer process in (NaCl- KCl)equimol-NaF (10 wt. %) — K2TiF6, KCl-KF (10 wt. %) — K2TiF6 and CsCl-CsF (10 wt. %) — K2TiF6 melts were calculated.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.