Abstract

We present the results of zero-field μ +-SR measurements on CoCO 3 and NiCO 3. Both compounds are rhombohedral antiferromagnets which exhibit a spontaneous weak magnetisation below 22.2 and 17.2 K , respectively. This arises due to an anisotropic superexchange (Dzyaloshinsky–Moriya) interaction. We have studied the temperature dependence of the internal field in the ordered state and the magnetic fluctuations in the paramagnetic state. We describe the possible muon-site obtained from dipolar-field calculations.

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