화학침착법과 고분자함침 열분해법의 복합공정으로 제조한 SiCf/SiC 복합체의 제조 공정에 따른 파괴거동

Abstract

SiC f /SiC composites were prepared using the hybrid process of chemical vapor infiltration (CVI) and polymer impregnation and pyrolysis (PIP). Before the application of PIP, partially matrix-filled preform composites with different densities were fabricated by control of chemical vapor infiltration time and temperature. The changes of the final density of the SiC f /SiC composites had a tendency similar to that of preform composites partially filled by CVI. Composites with lower density after the CVI process had a larger increment of density during the PIP process. Three types of microstructures were observed on the fractured surface of the composite: 1) well pulled-out fibers and lower density, 2) slightly pulled-out fibers and higher density, and 3) only bulk SiC. The different fractions and distributions of the microstructures could have an effect on the mechanical properties of the composites. In this study, SiC f /SiC composites prepared using a hybrid process of CVI and PIP had density values in the range of 1.05 ~ 1.44 g/㎤, tensile strength values in the range of 76.4 ~ 130.7 MPa, and fracture toughness values in the range of 11.2 ~ 13.5MPa·m 1/2 .