Abstract
We have designed and synthesized donor–acceptor conjugates having donor pyrene at the pyrrole-β position of either free-base porphyrin or Zn(II) porphyrin using vinylene spacer. Both the dyads have been completely characterized by elemental analysis, MALDI-MS, UV-Vis., and fluorescence (steady state and time-resolved) spectroscopies as well as cyclic voltammetry. The absorption maxima of both dyads are red-shifted by 8–12 nm. The ground state properties showed that there exist minimum π–π interaction between the aromatic subunits of these D–A systems. Quenched emission was observed in both the dyads when excited at 290 nm. The quenched emission explained in terms of intramolecular excitation energy transfer competes with the photo-induced electron transfer reaction in these D–A system.
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