Abstract
The structure, IR absorption and luminescence spectra of Pr0.99xLuxEu0.01BO3 orthoborates synthesized at 970°C were studied at 0 ≤ x ≤ 0.99. An increase in the concentration of lutetium leads to a sequential change of the structural state of the orthoborates. At first, the orthoborates are single-phase and have an aragonite structure (0 ≤ x ≤ 0.1). Then, they become two-phase and contain the aragonite and vaterite phases (0.1 < x < 0.6). With a further increase in х (0.6 < x ≤ 0.8), the compounds are single-phase with a vaterite structure, then they contain the vaterite and calcite phases (0.8 < x ≤ 0.95), and, finally, they become single-phase with a calcite structure (0.95 < x ≤ 0.99). An unambiguous correspondence between the structural modification and IR spectra of these compounds was established. It is shown that the emission of Eu3 + ions is observed in samples where the concentration of europium exceeds that of praseodymium.
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