Abstract
Terpene-based polyesteramides (PEAs) are sustainable and have a variety of favorable properties, making them suitable for a wide range of applications and for contribution to a much more sustainable polymer industry. This work focuses on the synthesis of the lactam from β-pinene and its copolymerization with ε-caprolactone. An important step in synthesizing β-pinene lactam is the oxidation ofβ-pinene to nopinone. To make the established oxidative cleavage more sustainable and efficient, the required amounts of Al2 O3 and KMnO4 are significantly reduced by using H2 SO4 as a catalyst. For the Beckmann rearrangement various catalysts and co-reagents are screened. Among these, the reaction with tosyl chloride is found the most favorable. Subsequently, the chain lengths of the β-pinene-based PEAs are remarkably increased from 6000 g mol-1 to more than 25100 g mol-1 by fine-tuning reaction time, temperature, and decreasing catalyst and initiator concentrations. Also, different catalysts for polymerization are tested. The resulting material shows melting temperatures of ≈55 °C and decomposition temperatures of 354 °C or higher. Processing via melt pressing or casting turned out to be quite difficult due to the polymer's brittleness. Furthermore, regarding biomedical applications, blends of PEA with polyethylene glycol were successfully prepared, yielding a more hydrophilic material.
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