Abstract

The solution property of MgO containing materials into the CaO-Fe2O3 system and the melting property of MgO containing sinter during reduction were investigated. The results obtained are summarized as follows:(1) The formation of high viscosity silicate and magnetite prevents the homogenization of slag and therefore, Cr slag and Ni slag remain unslagged. The formation of dicalcium ferrite prevents the dissolution of periclase into the CaO-Fe2O3 system.(2) During reduction unslagged MgO makes the shell of MgO-FeO solid solution with FeO in glassy silicate and its solution is negligibly low.(3) For both normal sinter and pellet, all silicate minerals dissolve above about 1240°C.(4) MgO addition in sinter is effective to decrease the slag quantity during reduction but the melting property of sinter is not so improved as that of pellet. The proper basicity for sinter and pellet is about 1.4.

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