Abstract
The results of Mössbauer studies of the composition and magnetic structure of Fe3O4 / -Fe2O3 nanoparticles placed in an external magnetic field with a strength of 1.8 kOe, which is a continuation of the work [A.S. Kamzin, I.M. Obaidat, A.A. Valliulin, V.G. Semenov, I.A. Al-Omari. FTT No. 10/2020]. It is shown that the thickness of the maghemite (-Fe2O3) shell can be changed by the synthesis conditions. It was found that on the surface of the maghemite (-Fe2O3) shell in the Fe3O4 / -Fe2O3 nanocomposites there is a layer in which the magnetic moments are not oriented collinearly to the moments located in the depth of the shell, i.e., there is a canted spin structure. An intermediate layer in the spin-glass state is formed between the core and the shell. The data obtained on the structure of core / shell particles are important for understanding the properties of nanocomposites, which are of great interest for applications in various fields, including biomedicine.
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