Abstract

Abstract Syntheses, properties, structure aspects and reactivity of non- and aromatically carbo- and heterocyclic annulated 1H- and 3H-1,3-azaphospholes are compared to illuminate the impact of annulation, substituent effects, aromatic stabilization and π-excess at phosphorus of the 1H-isomers, to demonstrate the current knowledge and open questions in this field of research.

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