Abstract
The new triple-bridged dinuclear cation [(η6-C6Me6)2Ru2(μ2-p-S–C6H4–OH)(μ2-PPh2)(μ2-H)]+, isolated and characterized as the tetrafluoroborate salt, was prepared by reacting the precursor [(η6-C6Me6)2Ru2(μ2-H)2(μ2-PPh2)](BF4) and p-hydroxythiophenol in refluxing ethanol. The single-crystal X-ray structure analysis of [(η6-C12H18)2Ru2(μ2-S–C6H4–OH)(μ2-H){μ2-P(C6H5)2}](BF4) shows the formation of the meso form; despite the two stereogenic centres the complex is not chiral.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Acta Crystallographica Section E Structure Reports Online
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
