Abstract
A surprisingly simple approach—heating per-2,3-anhydro-(2S)-β-cyclodextrin in water at reflux—provides the novel cyclooligosaccharide β-cycloaltrin (1) in 73% yield. In this one-step hydrolysis, ring opening results in the altro configuration in every sugar unit. The inclusion properties of 1 should be interesting.
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Schedule a callMore From: Angewandte Chemie International Edition in English
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