Abstract
An ethynylene-bridged zinc porphyrin dimer bearing metal-coordinating groups, such as bis[{5-(4-pyridyl)-15-(3,5-didodecyloxyphenyl)porphyrinato}zinc] Z2, self-assembles in CHCl 3 to form a rectangular-shaped supramolecular nano box, in which all the Z2 units preferentially adopt a planar conformation with a syn-parallel geometry as for the pyridyl groups.
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