Abstract

AbstractThe heat capacity and the permittivity of multiferroics Bi_1 – x Er_ x FeO_3 ( x = 0, 0.10, and 0.15) have been studied in the temperature range 130–800 K. It is found that an insignificant substitution of erbium for bismuth significantly increases the heat capacity in a wide temperature range T > 300 K. The temperature dependence of the excess heat capacity is shown to be due to manifestation of the three-level states. An additional anomaly characteristic of a phase transition has been revealed in the temperature dependences of the heat capacity and the permittivity for the compositions with x = 0.15 at T = 587 K. The results of studies are discussed in combination of the data of structural studies.

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