Abstract
The title compound, [Os3(C25H22As2)(CO)10], contains a triangle of singly bonded Os atoms; both arsine ligands are equatorial with respect to the Os3 triangle. Each arsine-substituted Os atom bears one equatorial and two axial terminal carbonyl ligands, whereas the unsubstituted Os atom bears two equatorial and two axial terminal carbonyl ligands. The dihedral angles between the two benzene rings in the diphenylarsino groups are 67.42 (16) and 61.99 (16)°. In the crystal, molecules are linked via C—H⋯O hydrogen bonds into zigzag chains propagating along [010].
Highlights
Structure ReportsMolecules are linked via C—H O hydrogen bonds into zigzag chains propagating along [010]
The title compound, [Os3(C25H22As2)(CO)10], contains a triangle of singly bonded Os atoms; both arsine ligands are equatorial with respect to the Os3 triangle
The dihedral angles between the two benzene rings in the diphenylarsino groups are 67.42 (16) and 61.99 (16)
Summary
Molecules are linked via C—H O hydrogen bonds into zigzag chains propagating along [010]
Sign-in/Register to view highlights & summary Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Acta Crystallographica Section E Structure Reports Online
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
