Abstract

The crystal structure of the title compound, [Cu 2 (C 2 Cl 3 O 2 ) 4 (C 6 H 4 N 2 ) 2 (H 2 O)].2CHCl 3 , was determined by single-crystal X-ray diffraction. Two Cu atoms, separated by a distance of 3.567 (2) A, are bridged by a water molecule and two trichloroacetate ions to form a local binuclear unit. The binuclear units are linked by 3-cyanopyridine molecules to form a two-dimensional network. The coordination geometry around Cu is tetragonally elongated octahedral. The spin-exchange interaction between the Cu atoms in the local binuclear unit is weakly antiferromagnetic

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