Abstract

Reaction of the μ-vinylidene complexes [Mo2(η5-C5H5)2(μ-SMe)3(μ-η1:η2-CCHR)](BF4) (1; R = Tol (1a), n-Pr (1b)) with NaBH4 produced the μ-alkylidyne derivatives [Mo2(η5-C5H5)2(μ-SMe)3(μ-CCH2R)] (2; ...

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