Abstract
Decomposition of benzylpenicillin in aqueous solution with N-substituted aniline or alkylamine results in the formation of benzylpenicilloic acid, N-formyl-d-penicillamine, and benzylpenillic acid. Benzylisopenilloic acid is formed by the application of N-disubstituted anilines and alkylamines. Some considerations were made on the relationship between the yield of benzylpenillic acid and pKa' value, and the mode of decomposition of procaine benzylpenicillin.
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