Abstract
The molecule of the title compound, [NaNi(C18H18N2O4)(ClO4)(CH3OH)], is almost planar, the maximum deviation from the molecular plane being 5.3 (1) Å. The Ni2+ ion is N2O2 coordinated by the Schiff base ligand, leading to a slightly distorted square-planar environment. The Na atom is chelated by the four O atoms of the Schiff base ligand and is coordinated by the O atoms of a methanol ligand and a perchlorate anion. The perchlorate ion is disordered over two sites with occupancies 0.723 (12):0.277 (12).
Highlights
The molecule of the title compound, [NaNi(C18H18N2O4)(ClO4)(CH3OH)], is almost planar, the maximum deviation from the molecular plane being 5.3 (1) Å
The Ni2+ ion is N2O2 coordinated by the Schiff base ligand, leading to a slightly distorted square-planar environment
The Na atom is chelated by the four O atoms of the Schiff base ligand and is coordinated by the O atoms of a methanol ligand and a perchlorate anion
Summary
Key indicators: single-crystal X-ray study; T = 273 K; mean (C–C) = 0.007 Å; disorder in main residue; R factor = 0.053; wR factor = 0.159; data-to-parameter ratio = 11.5. The molecule of the title compound, [NaNi(C18H18N2O4)(ClO4)(CH3OH)], is almost planar, the maximum deviation from the molecular plane being 5.3 (1) Å. The Ni2+ ion is N2O2 coordinated by the Schiff base ligand, leading to a slightly distorted square-planar environment. The Na atom is chelated by the four O atoms of the Schiff base ligand and is coordinated by the O atoms of a methanol ligand and a perchlorate anion. The perchlorate ion is disordered over two sites with occupancies 0.723 (12):0.277 (12)
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