Abstract
1) Application of alkylmagnesium bromides respectively to 2-diethylamino-, 2-piperidino-, and 2-morpholino-methylcyclohexanone yielded the corresponding 1-alkyl-2-diethylamino-, -2-piperidino-, and -2-morpholino-methylcyclohexanols. The latter was converted to a series of esters by condensation with aromatic acid chlorides.2) Application of acetyl or isovaleryl chloride or ethyl chlorocarbonate to 2-alkyl-(or benzyl)-2-dimethylaminomethylcyclohexanols yielded the corresponding esters.3) Application of ethyl chlorocarbonate respectively to 1-alkyl-1-p-aminobenzoyloxy-2-dimethyl (or diethyl) aminomethylcyclohexanes gave the urethanes. β-Bromopropionyl ester was obtained by the application of β-bromopropionyl chloride to 1-ethyl-2-dimethyl-aminomethylcyclohexanol and condensation of dimethylamine to the ester yielded 1-β-dimethylaminopropionyloxy derivative.
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