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Abstract
The title centrosymmetric dinuclear complex, [Mn2(C20H30N12)(H2O)4]Cl2·6H2O, consists of a dimanganese(II) macrocyclic complex in which the MnII centres are linked by two triazolate units of the macrocyclic framework. In the complex, the MnII cation is coordinated by five N atoms from the macrocycle and two O atoms from the coordinated water molecules. The MnII centre is in an approximately pentagonal–bipyramidal environment. Adjacent ions and water molecules are linked to form a one-dimensional chain via O—H⋯O and O—H⋯N hydrogen bonds.
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