Year-end Sale % OFF 
Abstract
Organotion-compounds coordinated by Lewis bases are far active substrates in comparison with non-coordinated ones. (1) The addition of tributyltin ω-haloalkoxides to heterocumulenes was accelerated in coordinative solvents. (2) The complexes of organotin iodides with phosphine oxides could act as talent catalysts for the cycloaddition of a variety of oxiranes and heterocumulenes, where selective β-cleavage of oxiranes was promoted. (3) Adding HMPA, tributyltin hydride exhibited highly ionic reactivity to reduce only the carbonyl moiety in α-chloro ketones.Catalytic use of tetraphenylstibium iodide allows for novel cycloadditions; (1) cycoladdition of carbon dioxide with oxetanes, (2) cycloaddition of heterocumulenes with monosubstituted oxiranes via selective α-cleavage of oxiranes.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
