Abstract

The results of the analysis and assessment of long-term changes in the qualitative characteristics of the Oka River runoff are presented. To analyze the temporal dynamics of the variability of the average annual and maximum concentrations of pollutants in the runoff of the Oka River, we used long-term observational data on typical pollutants for the period 1984-2019. The assessment of the state of the quality of surface waters of the Oka River was carried out according to the values of the concentrations of pollutants in the upper, middle and lower reaches of the river. The dynamics of the main pollutants of the following indicators is considered: ammonium nitrogen, oil products, copper and zinc compounds and easily oxidized organic substances. It was found that in the upper reaches of the river (according to observations of the Oka – Orel city) the main pollutants are ammonium nitrogen and copper compounds, the average annual concentrations of which respectively increased to 9 values. A similar situation was observed downstream of the river (the Oka River – Kaluga city). As a result of the analysis, it was revealed that more noticeable changes in the concentration of pollutants are observed in the section of the river from the city of Murom to the city of Dzerzhinsk. Near the city of Murom, the content of oil products in the water sharply increases. From the beginning of the study period (1984) and until 1995, the average annual concentration varied from 5 to 30 values, and the maximum concentration in the year in creased to 87 values. After 2000, the content of oil products in water dropped sharply and the average annual value did not exceed 3 values, and the maximum concentration was 4-6 values. The paper analyzes the frequency of cases of exceeding the maximum permissible concentrations of pollutants in the Oka River in the mouth of the river. There was a high repeatability of the content of copper compounds in water, which varied from 70 to 88%. The frequency of cases of excess of easily oxidized organic matter in the mouth of the Oka River varied from 64 to 74%. Relatively low, although stable, the repeatability of the content of oil products in water remained, which ranged from 23 to 42%.

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