Скачкообразные процессы магнитного разупорядочения, стимулированные магнитным полем в системах со структурной неустойчивостью

Abstract

A theoretical analysis of the features of structural and magnetostructural first-order phase transitions in magnetocaloric helimagnetic alloys of the Mn_{1-x}Cr_{x}NiGe system has been carried out. To describe the observed displacive structural transitions hex(P6_{3}/mmc)<->orth(P_{nma}), we used the local soft mode model in the approximation of a biased harmonic oscillator. In the absence of a magnetic field, the emergence of a helimagnetic order as a structurally induced second-order transition was described in the framework of the Heisenberg model, taking into account the dependence of the exchange integrals on the structural order parameters and elastic strains. In the presence of a magnetic field, it was found that the approximation of the characteristic temperatures for the helimagnetic HM(P_{nma}) and lability temperatures of the hexagonal paramagnetic PM(P6_{3}/mmc) states, due to the influence of the magnetic field, leads to the appearance of previously unexplored peripheral magnetostructural first-order phase transitions with insignificant magnetization jumps that increase with increasing magnetic induction.In this case, as the pressure increases to 4 kbar with constant induction of the magnetic field, the peripheral transitions transform into reversible first-order magnetostructural transitions, and at even higher pressures (10-14 kbar) into full-fledged first-order magnetostructural transitions with magnetization jumps comparable with maximum value of magnetization. Experimental pressure studies of the temperature dependences of magnetization in static magnetic fields with an induction of up to 1 T and a pressure of up to 14 kbar confirm the theoretical results.