Abstract
Diene is one of the most basic organic substrate including two carbon-carbon double bonds in its chain skeleton. Four π-electrons in its double bonds interact with metal atoms in various modes of bonding. Especially with early transition metals diene interact in unique fashion of bonding. These variety of bonding characteristics between diene and early transition metals reflect versatile utility of this type of complexes as the important reagents for new organic syntheses. This paper reviews the interaction of diene with early transition metals from the structure chemical point of view.
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