Abstract
The cell model is a kind of statistical thermodynamic model for the representation of a multi component ionic liquid. This model was applied to the CaO-Ca-CaX2(X: F, Cl) system to estimate the ternary phase diagram and thermodynamic properties. The energy parameters were determined by using the binary Ca-CaX2, CaX2-CaO and Ca-CaO phase diagrams and applied to the ternary phase diagram for the CaO-Ca-CaX2 system. Activity of calcium in the CaO-Ca-CaX2 at 1473 K was calculated and compared with the observed data. The applicability of the cell model was discussed.
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