Abstract
This article deals with novel organic reactions starting from α-hydroxymonothioacetals. Topics included are (1) preparation of α- (phenylthio) aldehydes from α-hydroxymonothioacetals, (2) stereocontrolled addition of methyltitanium reagents to α- (phenylthio) aldehydes, (3) synthesis of various allylic sulfides, (4) acyclic 1, 4-diastereoselective reduction in (E) -γ-substituted α-enones, (5) divergent synthesis of 1, 3- and 1, 4-diketones, (6) mechanistic insight into allylmetal-thioacetal reactions employing 2-acetoxy-2-phenylacetaldehyde thioacetals, and (7) synthesis of acetylenes and olefins through cross coupling of aldehydes.
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