Abstract

In the present study we investigated the hydrogen and methane production from sweet sorghum biomass. Sweet sorghum is an annual plant, characterized by high photosynthetic efficiency. Sweet sorghum biomass is rich in readily fermentable sugars and thus it can be considered as an excellent raw material for biofuels generation. It is the first time that this plant is used for the production of hydrogen, although ethanol and methane are among the best-known microbial products produced from sweet sorghum. Τhe fermentative production of hydrogen was achieved using an indigenous mixed microbial culture. The present study concerns the fermentative production of hydrogen from the sugars contained in sorghum extract. The process took place in a mesophilic continuous stirred tank type bioreactor, by an indigenous mixed microbial culture and it was studied at various conditions. Τhe subsequent anaerobic treatment of the effluent of the fermentative hydrogenogenic reactor with the simultaneous production of methane was investigated in a continuous stirred tank type reactor operated at three hydraulic retention times. The recently developed anaerobic model ADM1 was used to simulate the anaerobic digestion process and the fermentative hydrogen production process. However the structure of the model was modified, in order to improve the predictions for biohydrogen production. Finally, technoeconomic analysis was performed to determine the potential economic viability of the process. Biohydrogen and methane production from sweet sorghum biomass was not economic feasible; therefore improvement of the process design is necessary.

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