Abstract
The paper provides a detailed description of the reprojection method for the exact solution of the nonadiabatic nuclear dynamics within the Born–Oppenheimer formalism. In particular, it discusses the asymptotic behaviour of a state-to-state transition probability when a nonadiabatic radial coupling for this transition has a nonzero asymptotic value—a fundamental feature of the Born–Oppenheimer approach. It is known that the conventional Born–Oppenheimer approach leads to divergency of inelastic cross sections and inelastic rate coefficients, while the reprojection method provides convergences. The article describes physical background of the reprojection method.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
